Volume 604
Main Index

Issue 1, Pages 1-139 (5 June 2000)

Syntheses and crystal structure of bridged Os3-clusters with chiral 3-carane-type ligands Pages 1-6 Vladimir A. Maksakov, Vladimir P. Kirin, Pavel A. Petukhov, Tatjana V. Rybalova, Yuri V. Gatilov, Alexey V. Tkachev

Alkyl migration reactions—the direct observation of the preferential migration of branched over linear alkyl groups Pages 7-11 Emily J. Cammell, Jo-Ann M. Andersen

Synthesis and structure of ansa-metallocene complexes (M=ZrCl2, TiCl2, YCl, and LuCl) containing the bis(2-methyl-4,5,6,7-tetrahydroinden-yl)dimethylsilane ligand Pages 12-19 Ronald L. Halterman*, Herbert Schumann*, Frank Dübner

Synthesis, structure, and photochemical reaction of 9,10-dihydro-9-silaanthracene derivatives carrying bulky substituents Pages 20-26 Kozaburo Nishiyama, Makoto Oba, Hidenori Takagi, Isao Fujii, Noriaki Hirayama, Narisu, Hiroaki Horiuchi, Tetsuo Okutsu, Hiroshi Hiratsuka

59Co-NMR spectroscopy of the tetrahedral cluster Co4(CO)12: relaxation and exchange Pages 27-33 Christina Sizun, Pierre Kempgens, Jésus Raya, Karim Elbayed, Pierre Granger, Jacky Rosé

The organometallic double metal cyanide [(Me2Sn)3{Co(CN)6}2·6H2O]. A three-dimensional framework of infinite, stapled ribbons Pages 34-42 Eric Siebel, R. Dieter Fischer*, Nicola A. Davies, David C. Apperley, Robin K. Harris*

Reactions of trifluorovinyl-trifluoromethylboron derivatives, structure of (F2C=CF)(F3C)2B·NHMe2 and (HOOC)(F3C)2B·NHMe2 Pages 43-51 David J. Brauer, Gottfried Pawelke

Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(η5-C5Me5)Re(NO)(PPh3)(=C=C=C=C=CAr2)]+BF4− (CAr2=9-fluorenylidene) Pages 52-58 Slawomir Szafert, Pierre Haquette, Stephen B. Falloon, J. A. Gladysz

Novel 18-crown-6 organometallic rubidium and cesium complexes containing cyclopentadienyl, indenyl, pentamethylcyclopentadienyl, and fluorenyl as carbanions Pages 59-67 Swen Neander, Ulrich Behrens, Falk Olbrich

Darstellung und Eigenschaften Heterobimetallischer Komplexe — Kristallstruktur von [(acac)3Zr---OCCo3(CO)9] Pages 68-71 Katy Kluwe, Karl-Heinz Thiele, Angela Sorkau, Attila Sisak, Bernhard Neumüller

Phosphane coordination to rare earth metal centers: monomeric, solvent-free complexes of type Cp′2LnX with phosphanoethyl substituted cyclopentadienyl ligands Pages 72-82 Hans H. Karsch, Volker W. Graf, Wolfgang Scherer

Diverse catalytic activity of the cationic actinide complex [(Et2N)3U][BPh4] in the dimerization and hydrosilylation of terminal alkynes. Characterization of the first f-element alkyne π-complex [(Et2N)2U(CCtBu)(η2-HCCtBu)][BPh4] Pages 83-98 Aswini K. Dash, Jia Xi Wang, Jean Claude Berthet, Michel Ephritikhine, Moris S. Eisen

Rhodium-catalyzed reduction of α-amino acid precursors using chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligands Pages 99-102 Fabien Robert, Denis Sinou

Synthetic and reactivity studies of mono- and dicyclopentadienyl titanium, zirconium and hafnium complexes with the chlorodimethylsilyl-cyclopentadienyl ligand. X-ray molecular structure of Hf{(η5-C5H4)SiMe2OSiMe2(η5-C5H4)}Cl2 and Zr(η5-1,3-tBu2C5H3)(η5-C5H4SiMe2-η-NtBu)Cl Pages 103-115 Santiago Ciruelos, Alfredo Sebastián, Tomás Cuenca, Pilar Gómez-Sal, Antonio Manzanero, Pascual Royo

Formation of elastomeric polypropylene promoted by the dynamic complexes [TiCl2{N(PPh2)2}2] and [Zr(NPhPPh2)4] Pages 116-125 Olaf Kühl, Thomas Koch, Fernando B. SomozaJr., Peter C. Junk, Evamarie Hey-Hawkins*, Dorit Plat, Moris S. Eisen*

Chelated η5-cyclopentadienyl-η-ethyl complexes of molybdenum and tungsten; molecular structure of W(η5-C5H4CH2-η-CH2)(CO)3 Pages 126-131 Francisco Amor, Pascual Royo, Thomas P. Spaniol, Jun Okuda

Synthesis and structure of fluorinated dialacycles Pages 132-136 Martin Tschinkl, T. Matthew Cocker, Robert E. Bachman, R. E. Taylor, François P. Gabbaï

Index Page 139

Issue 2, Pages 141-311 (16 June 2000)

Unprecedented effects of the trimethylsilyl group on the reactivity of 3C-silylated silacyclopentenes and their derivatives Pages 141-149 Rabah Boukherroub, Georges Manuel

Syntheses and reactions of ruthenium complexes containing C6 and C8 chains Pages 150-156 Michael I. Bruce, Brian D. Kelly, Brian W. Skelton, Allan H. White

Novel synthesis of indazoles from (η6-arene)tricarbonylchromium complexes Pages 157-169 M. Rute G. da Costa, M. João M. Curto, Stephen G. Davies, M. Teresa Duarte, C. Resende, Fátima C. Teixeira

Metal-induced B---H activation. Addition of phenylacetylene to Cp*Rh-, Cp*Ir-, (p-cymene)Ru- and (p-cymene)Os halfsandwich complexes containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate ligand Pages 170-177 Max Herberhold*, Hong Yan, Wolfgang Milius, Bernd Wrackmeyer*

Oxidative addition of alkyl halides to chiral cyclometallated platinum(II) complexes with thienyl imines. X-ray crystal structure of [PtMe{3-((S)-PhCHMeNCH)C4H2S}SMe2] Pages 178-185 Craig Anderson, Margarita Crespo, Mercè Font-Bardía, Xavier Solans

Réactivité du 3,3-bis(triméthylsilyl)propène vis-à-vis des ions iminium issus d'amines secondaires. Accès stéréosélectif à des (E)-β-aminovinylsilanes Pages 186-190 Bruno Princet, Hélène Gardès-Gariglio, Jacques Pornet

2,2′:6′,2″-Terpyridine complexes of molybdenum(II) and tungsten(II). X-ray crystal structures of [MoI(CO)(terpy)(η2-PhC2Ph)]I and [WI(terpy)(η2-PhC2Ph)2]I·CDCl3 Pages 191-196 Nicholas Aimeloglou, Paul K. Baker, Michael G. B. Drew, Bjoern Glaeser, Fiona Holland, Margaret M. Meehan

Synthesis and crystal structures of [Rh(TTP)(CH3)]2(μ-CNpy) and [Rh(TTP)(C8H11)] (TTP=5,10,15,20-tetra(p-tolyl)porphyrin dianion; CNpy=4-cyanopyridine; C8H11=(5-norbornen-2-yl)methyl) Pages 197-201 Wa-Hung Leung, Willetta Lai, Ian D. Williams

First structural characterization of completely alkyl-substituted Al–Sb Lewis acid–base adducts Pages 202-207 Stephan Schulz, Andreas Kuczkowski, Martin Nieger

Carbanion mechanisms XXI. Solution acidity of triphenylsilane Pages 208-210 Erwin Buncel, T. K. Venkatachalam

Reaction of trimethylsilyl azide with a digermene in the presence of water: 1,2-addition of hydrazoic acid Pages 211-213 Helmut Schäfer, Wolfgang Saak, Manfred Weidenbruch

Reaction of [(μ-RE)(μ-CO)Fe2(CO)6]− (E=S, Se) with N2CHCO2Me. Synthesis and characterisation of (μ-RE)[μ-η2-N=NCH(R′)CO2Me]Fe2(CO)6 and (μ-PhSe)[μ-η1-N=NCH(Me)CO2Me]Fe2(CO)6 Pages 214-218 Zhong-Xia Wang, Shao-Bin Miao, Ze-Ying Zhang

Mixed carbonyl–nitrile complexes of dirhenium(II). The structural characterization and reactivity of salts of the [Re2Cl3(μ-dppm)2(CO)(NCMe)n]+ cations (dppm=Ph2PCH2PPh2, n=1 or 2) Pages 219-228 James Chantler, Phillip E. Fanwick, Richard A. Walton

Rigid five-coordinate diorganotin derivatives of oxalic acid diamides, studied by 119Sn-NMR and X-ray structural analysis Pages 229-233 Rosalinda Contreras*, Victor M. Jimenez-Perez, Carlos Camacho-Camacho, Marisol Güizado-Rodriguez, Bernd Wrackmeyer*

Cationic molybdenum complexes with P-coordinated (diphenylphosphino)alkynes Pages 234-240 Elmostafa Louattani, Joan Suades

Reactions of nickelocene with diphenylmethyl- and triphenylmethyllithium Pages 241-247 Stanisaw Pasynkiewicz, Antoni Pietrzykowski, Lidia Bukowska, Konrad Supecki, Lucjan B. Jerzykiewicz, Zofia Urbaczyk-Lipkowska

Schiff base linked ferrocenyl complexes for second-order nonlinear optics Pages 248-259 Sushanta K. Pal, Anu Krishnan, Puspendu K. Das, Ashoka G. Samuelson

Synthesis, structure and reactions of 1-(p-chlorophenyl)-3-(2,4,6-tri-t-butylphenyl)-1-aza-3-phospha-allene Pages 260-266 Xi-Geng Zhou, Li-Bei Zhang, Rui-Fang Cai, Qiang-Jin Wu, Lin-Hong Weng, Zu-En Huang

Structures and spectroelectrochemistry (UV–vis, IR, EPR) of complexes [(OC)3ClRe]n(abpy), n=1, 2; abpy=2,2′-azobispyridine Pages 267-272 Heiko Hartmann, Thomas Scheiring, Jan Fiedler, Wolfgang Kaim

Synthesis and molecular structures of dimeric boron compounds Pages 273-282 Victor Barba, Rolando Luna, Dolores Castillo, Rosa Santillan, Norberto Farfán

Decomposition of the crown ether ring in the reaction of K−, K+(15-crown-5)2 with oxetane Pages 283-286 Zbigniew Grobelny, Andrzej Stolarzewicz, Adalbert Maercker

Two convenient new syntheses of ferrocenoyl chloride by triphosgene Pages 287-289 Wang Qingmin, Huang Runqiu

The mechanism of C---C bond formation on the Pt(IV) center involving chelate metallocycle ligands Pages 290-295 Valentine P. Ananikov, Sergey A. Mitchenko, Irina P. Beletskaya

Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente: L. Experimentelle Erfassung und Simulation der Elektronenstruktur des ersten metallorganischen π-Komplexes eines Lanthanids der zweiten Halbserie: (η5-Cp)3Er·CNC6H11 Pages 296-299 Hauke Reddmann, Holger Schultze, Hanns-Dieter Amberger, Norman M. Edelstein

Heterogeneous Catalysis in Organic Chemistry, G.V. Smith and F. Notheisz, Academic Press, San Diego, 1999, pp. 346. ISBN 0-12-651645-6; US$89.95. Page 300 Horst Kisch

Erratum to: “Kohlenwasserstoffverbrückte Metallkomplexe, XLVIII. Addition von Bis(ferrocenyl)-1,3-diketonen und von Metalldiketonaten an koordinierte, ungesättigte Kohlenwasserstoffe von kationischen Komplexen”: [J. Organomet. Chem. 599 (2000) 238–246] Page 301 Oliver E. Woisetchläger, Andreas Geisbauer, Kurt Polborn, Wolfgang Beck

Index Pages 304-305

Index Pages 306-311